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Devetzi was born on [[January 2]], [], in [[Alexandroupolis]], [[Thrace]]. She competes on the club level for Olympiakos [[Piraeus]].
She won the triple jump silver medal at the [[Athletics at the 2004 Summer Olympics|2004 Summer Olympics]] with a
personal best of 15.25m, after setting the Greek record in the preliminaries with a jump of 15.32m. on [[August 9]], [], she won another silver medal at the 2006 European Athletics Championships in Gothenburg.